Evaluation of stress corrosion cracking damage to an api 5l. The austenitic stainless steels are impact tough at cryogenic temperatures. It is typically considered resistant to ammonia stress corrosion cracking. Effect of anhydrous ammonia composition on its ability to cause. Further progress is then a process alternating between corrosion and mechanical cracking until the material fails completely. I dont remember any ss except the reformer furnace tubesmanifolds hk40 hp mod. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in cooling water service that has been contaminated with ammonia due to biological growths or other contamination. Stress corrosion cracking issues in syngas plants that may be. The cracks are small at the surface but can be deep, worstcase going through the entire thickness of the metal. Ammonia at high temperature has high potential for nitriding metals. However, stress corrosion cracking continues to be a problem in aging plants and must be considered when completing risk based inspection rbi. The stress corrosion cracks are found mainly in the welds, and the attack is dependent upon the type of steel, the impurities in the ammonia, and the stresses in the.
The specificity of environments that will promote stress corrosion cracking is significant. It has been shown that, for some materials, fine pitting is needed to start the activity. Ammonia is not corrosive for stainless steel without presence of water or condensate. Stress corrosion cracking in refrigeration systems request pdf.
Generally, scc provokes cracks and fractures with a sudden structure rupture 2 4. Ammonia stress corrosion cracking a mmonia stress corrosion cracking scc is the phenomena of cracks being formed in carbon steel in contact with ammonia. Stainless steels in ammonia production nickel institute. Stress corrosion cracking of carbon steel storage tanks for anhydrous ammonia. Anhydrous ammonia in carbon steels and quenchedandtempered lowalloy steels in the presence of air in addition to stress, oxygen is a critical ingredient to enable scc nitrogen aggravates the process source. Impurities in ammonia, such as air or carbon dioxide, can cause stress corrosion cracking. Astm b858 062018 standard test method for ammonia vapor. The formation of cupric complex ions leads to stress corrosion cracking of brass in ammonia solutions. Season cracking is also known as stress corrosion cracking or environmental cracking. The stress corrosion cracking scc behavior of electricresistancewelded erw api grades x42, x46, x52, and x60 linepipe in liquid ammonia has been evaluated for the base metal, erw weldments, and girth weldments. A stateoftheart report on stress corrosion cracking scc of carbon and low alloy steels in anhydrous ammonia service.
Stress corrosion cracking has been detected in ammonia storage tanks, spheres and other process equipment that is in contact with liquid ammonia. The wol specimens were not effective in predicting stress corrosion cracking in the liquid ammonia environment. At high pressure, corrosive ammonium carbamate may be formed. As the result of the studies the research committee recommended 2 that.
Citeseerx stress corrosion crack tests of 16mnr low alloy. Evaluation of stress corrosion cracking damage to an api. The following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the. Predicted growth of throughthickness stress corrosion. Stresscorrosion cracking occurs in a susceptible material when it is exposed to sustained tensile stresses and a specific environment. Carbon steel, alloy steel, and highstrength, quenched and tempered steel, when under applied or residual stress and especially when cold formed andor welded without subsequent thermal stress relief, are subject to failure by stresscorrosion cracking scc in aircontaminated dry ammonia. The highest susceptibility to scc was found in liquid ammonia with 310 ppm oxygen and a water content lower than 100 ppm. A compressive stress does not cause stress corrosion cracking. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented in design codes, safety standards and textbooks and ways in which the initiation of. Carbon steel in anhydrous ammonia can suffer from scc stress corrosion cracking. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Electrochemistry of stress corrosion cracking of brass. Stresscorrosion cracking of steels in ammonia with.
Four factors, are required before stress corrosion cracking can occur. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented. This may result in ammonia weeping from a crack within the refrigeration system. The composition of the anhydrous ammonia is closely controlled to prevent attack on the pipeline. Generally, scc provokes 1 cracks and fractures with a. The following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Effect of anhydrous ammonia composition on its ability to. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
Stresscorrosion cracks in heat affected zone of astm a 202. Measures for reducing scc in anhydrous ammonia storage. Generally, scc provokes cracks and fractures with a. Introduction the following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Ammonia that is mixed with water is not corrosive to iron or steel.
This recapitulation of experiences with stress corrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Zinc, copper and brass are some materials that should not be brought into contact with ammonia that contains water because ammonia corrosion can occur. Prevention of stress corrosion cracking of carbon steels. Carbon and lowalloy steels scc can occur in other materials stainless steel. Anhydrous ammonia is one of the medium where the steel is easy to suffer stress corrosion cracking. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented in design codes, safety standards and textbooks and ways in which the initiation of stress corrosion can be prevented are ignored. Stress corrosion cracking of steel in liquefied ammonia. This new second edition serves as a goto reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application. Water in ammonia to protect against stress corrosion cracking. It is important to realize that not all corrosive environments promote the formation of stress corrosion cracks.
Stress corrosion cracking in refrigeration systems. The main issue is the cryogenic toughness of stainless steels at around 40 degc, compared to carbon steels, which can also be considered for ammonia service under these conditions. It can happen at atmospheric liquid ammonia conditions at 33 c, but also at higher temperatures under pressurized ammonia conditions. Ammonia and stainless steel, corrosion blacksmith37 materials dec 11 15. It is well known that the stress corrosion cracking scc mechanism is caused by the combination of tensile stress and a corrosive medium 1. This cracking can also occur when ammonia is intentionally added to process streams as a neutralizer by someone unaware of its potential effect on brass tubes. Scc stress corrosion cracking leaflet product stewardship. Stress corrosion cracking of steel in liquefied ammonia service a. Generally, scc provokes 1 cracks and fractures with a sudden structure rupture 24. The combined effect of water and oxygen on stress corrosion cracking of carbonmanganese steel in liquid and gaseous ammonia has been studied in detail. Care must be taken to ensure that pressure vessels are not subjected to this type of corrosion. Astm b858062018, standard test method for ammonia vapor test for determining susceptibility to stress corrosion cracking in copper alloys, astm international, west conshohocken, pa, 2018, back to top.
This type of failure is referred to as stress corrosion cracking scc. Season cracking occurs in copperbased alloys subjected to a residual or applied tensile stress and exposed to a specific environment, such as moist air containing traces of ammonia. Measures for reducing scc in anhydrous ammonia storage tanks. Again, corrosion alone in the absence of stress does not produce cracking. Anhydrous ammonia an overview sciencedirect topics. First, the part must be stressed, either from an applied force or due to residual stress usually from forming. His letter indicates that the tampa pipeline corporations plan to inhibit stress corrosion cracking in the pipeline amounts to. Stress corrosion cracking of carbon steel storage tanks for. Mercury stress corrosion cracking of brass components can also occur in service due to contamination from broken thermometers. This may result in a catastrophic failure of bulk storage vessels.
Numerous accidents have occurred in which nurse tanks failed and ammonia was released, often with explosive force. Corrosion selection of materials health and safety. Many stress corrosion crack accidents of ammonia storage tanks have been reported all over the world for recent years. Water in ammonia to protect against stress corrosion. According to the american society for metals metals handbook, desk edition, 4 intergranular fracture in carbon steel in the presence of a caustic material, such as anhydrous ammonia, is typical of stresscorrosion cracking. Stress corrosion cracking of astm a517 steel in liquid. Stress corrosion cracking of brass in ammonia ukessays. Stress corrosion tests have been performed on pressure vessel. Corrosion and stresscorrosion cracking scc tests were performed on aluminum drillpipe alloy 2014t6 in a waterbased, lowsolids, nondispersed lsnd drilling mud. The stress level at which the failure occurs is well below the stress required for a mechanical failure in the absence of corrosion. Even trace quantities of chlorides can cause problems at temperatures above 60c. Selection of stainless steels for handling ammonia nh3. Condensed ammonia is a corrodent, and in anhydrous state it can cause stresscorrosion cracking of stressed carbon steels or highstrength, lowalloy steels. Carbon steel, alloy steel, and highstrength, quenched and tempered steel, when under applied or residual stress and especially when cold formed andor welded without subsequent thermal stress relief, are subject to failure by stress corrosion cracking scc in aircontaminated dry ammonia.
The committee determined that the failures were most likely caused by stresscorrosion cracking and that the probability of cracking increased as the yield strength of the steel increased. Stress corrosion cracking the international institute of. Water can be added to the ammonia to help prevent stress corrosion cracking. Stress corrosion cracking in ammonia did not occur in steel specimens with fatigue precracks, due to a crevice corrosion attack. The mechanism of stress corrosion cracking scc involves a very complicated sequence of corrosion and fracture. Many metals suffer from stress corrosion cracking under certain conditions. Citeseerx document details isaac councill, lee giles, pradeep teregowda. Stress corrosion cracking of linepipe steels in anhydrous. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment.
Jul 11, 2011 the committee determined that the failures were most likely caused by stress corrosion cracking and that the probability of cracking increased as the yield strength of the steel increased. The intent is to provide the corrosion engineer with the information needed to make informed decisions in individual applications. Stress corrosion cracking, residual stress, ammonia transporting pipeline. Stress corrosion cracking sco of carbon and alloy steels in liquid ammonia has occurred spasmodically over the last twenty years. Predicted growth of throughthickness stress corrosion cracks. Stress corrosion cracking, residual stress, ammonia transporting pipeline 1. Stress corrosion cracking issues in syngas plants that may. A study was made to determine relevant growth data and to determine methods to prevent cracking. This is largely inhibited, however, if the ammonia contains 0.
The growth of stress corrosion cracks increased with stress intensity factor and decreased with exposure time. Citeseerx stress corrosion crack tests of 16mnr low. Ammonium hydroxide stainless steela ahow good resistance to all concentrations of ammonia. In piping the most frequent failures from stress corrosion cracking occur with austenitic stainless steels in contact with solutions containing chloride. Corrosion resistance and cryogenic toughness of stainless steels. While it is rare, formed parts can develop fractures after they are placed in service. Electrochemistry of stress corrosion cracking of brass m. Jul, 2017 season cracking occurs in copperbased alloys subjected to a residual or applied tensile stress and exposed to a specific environment, such as moist air containing traces of ammonia.
Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Typically the indication of a leak due to stress corrosion cracking is a strong smell of ammonia gas seeping through a short hairline crack on a pressure vessel. Anhydrous ammonia stress corrosion cracking scc incident. This recapitulation of experiences with stresscorrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Introduction it is well known that the stress corrosion cracking scc mechanism is caused by the combination of tensile stress and a corrosive medium. This occurs when contaminants in the ammonia are brought into contact with the steel, a situation that commonly occurs with pressure vessels. Extreme care should be used to eliminate air from the ammonia systems. Also tanks for transporting liquid ammonia, like rail tank cars.
Pressure vessels should be either fully stress relieved or fabricated with heads that are hotformed or stress relieved. Stress corrosion cracking international institute of. Oxygen levels of more than a few ppm in liquid ammonia or a few thousand ppm in gaseous ammonia can promote stress corrosion cracking in steels. Anhydrous ammonia is a toxic material that is transported from distribution centers to farm fields in steel pressure vessels called nurse tanks. The vessel can be isolated and taken out of service without any risk of catastrophic failure, but of course the economic consequences for the enduser. The process does not proceeds indefinitely since the attack of cupric complex ion oxide layer occurs at critical copper ion content which leads to decrease in corrosion rate but the cracking continues with the copper ion concentration. Further progress is then a process alternating between corrosion. Predicted growth of throughthickness stress corrosion cracks in. Cracking has been detected in ammonia storage tanks, spheres and other process equipment that is in contact with liquid ammonia. Blaine, wa 98230 abstract during the past decade, there has been evidence of stress.
Variables examined included chloride concentration, temperature, state of aeration, and effects of galvanic coupling to tooljoint steel. Stress corrosion cracking of carbon steel storage tanks. The majority of such accidents are caused by stress corrosion cracking of the tank steel. Stress corrosion crack growth of carbon steel in ammonia was studied with compact tension specimens. Department of transportation regulations provide effective safeguards to prevent this problem through the required use of postweld heat treatment and the use of 0.
Electrochemistry of stress corrosion cracking of brass by. Stress corrosion cracking in brass is usually localised and, if ammonia has been involved, may be accompanied by black staining of the surrounding surface. Stress corrosion cracking scc of the welds in carbon steel transport and storage tanks for anhydrous ammonia has been experienced worldwide for the last 30 years. Prevention of stress corrosion cracking of carbon steels in. Ammonia corrosion can cause stress corrosion cracking in steels.
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